期刊
SEPARATION SCIENCE AND TECHNOLOGY
卷 54, 期 16, 页码 2567-2576出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/01496395.2018.1548482
关键词
Fuel oil; poly ionic liquid; nitrogen compounds; adsorptive removal
资金
- National Natural Science Foundation of China [21666009]
- Natural Science Foundation of Jiangxi Province [20171BAB203021]
A poly ionic liquid, poly(1-vinyl imidazole)-p-xylylene dichloride (PVIm-PXDC), was synthesized and used for fuel oil denitrogenation. The structure of PVIm-PXDC was characterized and the denitrogenation performance was investigated. Results indicate that the pseudo-second-order kinetic model and Langmuir model are appropriate to describe the adsorption kinetics and thermodynamics, respectively. The adsorption ability of PVIm-PXDC for different nitrogen compounds follows the order of indole > pyrrole > quinoline > pyridine. The equilibrium adsorption amount decreased about 10% for all the nitrogen compounds after six regeneration cycles and the denitrogenation and regeneration processes have no influence on the structure of PVIm-PXDC.
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