期刊
ACTA CHIMICA SINICA
卷 74, 期 11, 页码 942-948出版社
SCIENCE PRESS
DOI: 10.6023/A16080406
关键词
polymorphism; pyrrolopyrrole; acid response; aggregation-induced emission
资金
- National Basic Research Program of China (973 Program) [2013CB834704]
- National Natural Science Foundation of China [51328302, 21474009]
A new A-D-A type pyrrolopyrrole-based derivative 4',4 ''-(2,5-diphenyl-pyrrolo[3,2-b]pyrrole-1,4-diyl)bis ([1,1'-biphenyl]-4-carbonitrile) (DPPDC) was synthesized via Suzuki coupling reaction between 1,4-bis(4-bromophenyl)-2,5-diphenyl-1,4-dihydropyrrolo[3,2-b]pyrrole and 4-cyanophenylboronic acid. The fluorescent emission intensities of DPPDC in pure THF solution and lower fraction of water (phi(H2O)<= 60%) mixtures were weak at around 550 nm. When phi(H2O) was 99% in THF/H2O mixtures, the emission was enhanced and blue-shifted at around 505 nm. The maximal fluorescent emission intensity of DPPDC was 11 times higher than that of in pure THF solution, indicating DPPDC exhibiting AIE property. It was also found that four different kinds of crystal structures of DPPDC was cultivated from CHCl2-Hexane, CHCl3-Hexane and CHCl3/Acetone-Hexane systems via solvent slow diffusion method. Four crystals respectively emitted blue, azure, green and turquoise at 467, 483, 496 and 493 nm, which manifested the polymorphism-dependent fluorescent emission property of DPPDC. Additionally, trifluoroacetic acid (TFA) could make the emitting color change from yellow to orange-red with as-prepared paper containing DPPDC due to the acid-base interaction. The obvious emitting color change of DPPDC can be used as a visual sensor to detect acid gas.
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