期刊
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
卷 12, 期 12, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/pssr.201800451
关键词
1D inorganic molecular chain; exfoliation; Nb2Se9; van der Waals bonding
资金
- Nano Material Technology Development Program through the National Research Foundation of Korea (NRF) - Ministry of Science and ICT [2017M3A7B8065561]
- National Research Foundation of Korea (NRF) - Korea government (MSIP) [NRF-2017R1A4A1015770]
A novel one-dimensional (1D) inorganic material, Nb2Se9, which can be separated into atomic-level, is synthesized through chemical reaction between Nb and Se sources. Nb2Se9 and Se crystals are formed under an excess Se condition to avoid other phase such as NbSe3, and the residual Se can be removed by heat treatment; thus, high-purity Nb2Se9 crystals can be obtained. The one-atom-thick level Nb2Se9 nanochains are successfully obtained by mechanical exfoliation and dispersion in a solvent. The covalently bonded Nb2Se9 chain, when isolated from its three-dimensional bulk material, is expected to have unique physical properties based on electron confinement in the 1D chain structure and the absence of dangling bonds. In addition, it has excellent thermal stability (up to 500 degrees C) and can be widely used in various fields.
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