期刊
ORGANIC PROCESS RESEARCH & DEVELOPMENT
卷 23, 期 1, 页码 38-44出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.oprd.8b00324
关键词
heterogeneous catalysis; multiphase hydrogenation; oscillatory baffled reactor; commercial Parr reactor
资金
- EPSRC Manufacturing Research Hub Programme [EP/K503289/1]
- EPSRC [EP/K503289/1] Funding Source: UKRI
A multiphase catalytic hydrogenation of 3-butyn-2-ol over Pd/Al2O3 to produce 3-buten-2-ol was for the first time investigated in both an oscillatory baffled reactor (OBR) and a commercial stirred tank reactor (Parr). Catalytic control was first identified in the Parr by evaluating the effects of mixing, initial molar ratio of 3-butyn-2-ol/Pd, and temperature on reaction rate. These conditions were then used as the benchmark for a comparable evaluation of the OBR in terms of reactor efficiency (power consumption) and hydrogen utilization (H-2 efficiency). Our systematic investigations demonstrate that, due to the enhanced mass transfer in the OBR, it consumes 5 times less power to achieve the same reaction rate and delivers 2.3 times higher H-2 efficiency and 50% less reaction time in comparison to the Parr.
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