期刊
ORGANIC LETTERS
卷 20, 期 23, 页码 7419-7423出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03141
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The diastereoselective synthesis of various substituted morpholines has been achieved from vinyloxiranes and amino-alcohols under sequential Pd(0)-catalyzed Tsuji-Trost/Fe(III)-catalyzed heterocyclization. Using the same strategy, 2,6-, 2,5-, and 2,3-disubstituted as well as 2,5,6- and 2,3,5-trisubstituted morpholines were obtained in good to excellent yields and diastereoselectivities.
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