期刊
ORGANIC LETTERS
卷 20, 期 22, 页码 7288-7292出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03216
关键词
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资金
- State Key Laboratory of Organometallic Chemistry
- Hundred Talents Plan of Chinese Academy of Sciences
- Shanghai Sailing Program [17YF1424100]
- National Natural Science Foundation of China [21702222]
- Science and Technology Commission of Shanghai Municipality [17JC1401200]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- Shanghai Institute of Organic Chemistry
- Thousand Youth Talents Plan
Catalytic chemo- and enantioselective generation of 1,3-disubstituted allyl-Cu complexes from a Cu-H addition to 1,3-dienes followed by in situ reactions with aldimines to construct homoallylic amines is presented. The method is distinguished by an unprecedented pathway to generate enantiomerically enriched allyl-Cu species, allowing reactions with a wide range of aldimines in high chemo-, site-, diastereo-, and enantioselectivity. Functionalization provides useful building blocks that are otherwise difficult to access.
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