期刊
ORGANIC LETTERS
卷 21, 期 2, 页码 428-433出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03610
关键词
-
资金
- Nano Material Development Program - Ministry of Education, Science and Technology, Republic of Korea [NRF-2012M3A7B4049644]
Transition-metal-free multicomponent reactions involving aryne precursors, secondary amines, and sulfuryl fluoride are reported herein. Zwitterionic intermediates formed from the reaction of arynes with amine nucleophiles can capture SO2F2 under mild conditions, offering a novel and practical protocol for the synthesis of 2-dialkyl-, 2-alkylaryl-, or 2-diarylamino-substituted arenesulfonyl fluoride derivatives in good to excellent yields.
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