期刊
ORGANIC LETTERS
卷 20, 期 21, 页码 6659-6662出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02670
关键词
-
资金
- National Natural Science Foundation of China [21625203, 21472039]
- Jiangxi Province Science and Technology Project [20171ACB20015, 20165BCB18007]
A new, three-component 1,2-alkylamination of styrenes with alkyl N-hydroxyphthalimide (NHP) esters and amines by Lewis acid and visible-light photoredox cooperative catalysis is described. This reaction employs alkyl NHP esters as general alkylation reagents to accomplish the 1,2-alkylamination of alkenes in high efficiency and with excellent functional groups tolerance, significantly enhancing the synthetic complex functionalized amines. potential of 1,2-alkylaminations of alkenes for accessing complex functionalized amines.
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