期刊
ORGANIC LETTERS
卷 20, 期 20, 页码 6511-6515出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02832
关键词
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资金
- CSIR-India
- SERB-India [EMR/2016/004298/OC]
- UGC-India
- IISERB
The total synthesis of the proposed structure of mycobactin J (MJ), a metabolite of Mycobacterium tuberculosis, is presented. The highlights of the synthesis include a careful control of the Z-stereochemistry of the unsaturated long chain fatty acid, a biomimetic construction of the oxazoline building block and the carriage of an unprotected phenol throughout the synthesis.
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