期刊
ORGANIC LETTERS
卷 21, 期 1, 页码 287-291出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03736
关键词
-
资金
- Japan Society for the Promotion of Science [18H01980]
- Grants-in-Aid for Scientific Research [18H01980] Funding Source: KAKEN
Reduction of nitriles to silylated primary amines was achieved by combination of 1,1,3,3-tetramethyldisiloxane (TMDS) as the hydrosilane and a catalytic amount of Co(OPiv)(2) (Piv = (COBu)-Bu-t) associated with isocyanide ligands. The resulting silylated amines were subjected to acid hydrolysis or treatment with acid chlorides to give the corresponding primary amines or imides in good yields. One-pot synthesis of primary amides to primary amines with hydrosilanes was also achieved by iron-cobalt dual catalyst systems.
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