期刊
MOLECULES
卷 24, 期 1, 页码 -出版社
MDPI
DOI: 10.3390/molecules24010164
关键词
amide bond; sulfonamide bond; alkynes; addition reaction; aminoacylation; aminosulfonylation
资金
- National Natural Science Foundation of China [21602022, 81620108027, 21632008]
- Sichuan Science and Technology Program [2018JY0345]
- Chengdu University New Faculty Start-up Funding [2081915037]
The addition of amide/sulfonamide bonds to alkynes is not only one of the most important strategies for the direct functionalization of carbon-carbon triple bonds, but also a powerful tool for the downstream transformations of amides/sulfonamides. The present review provides a comprehensive summary of amide/sulfonamide bond addition to alkynes, including direct and metal-free aminoacylation, based-promoted aminoacylation, transition-metal-catalyzed aminoacylation, organocatalytic aminoacylation and transition-metal-catalyzed aminosulfonylation of alkynes up to December 2018. The reaction conditions, regio- and stereoselectivities, and mechanisms are discussed and summarized in detail.
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