Triazine-based conjugated microporous polymers constructing triphenylamine and its derivatives with nitrogen as core for iodine adsorption and fluorescence sensing I2

Three new triazine-based conjugated microporous polymers with nitrogen as cores containing triphenylamine (TPA), 4,4',4 ''-tris(N,N-diphenylamino)triphenylamine (TDATA) and 4,4',4 ''-tri[phenyl(m-tonyl)amino]triphenylamine moieties (TMDATA) (TTPA, TTDATA and TTMDATA) were constructed via Friedel-Crafts reaction catalysed by methanesulfonic acid. The resulting CMPs possess high BET surface area of over 308, 491 and 456 m(2) g(-1), large pore volumes, good stability, and display efficient and reversible guest uptake of 4.92, 4.72 and 4.49 g g(-1) in iodine vapour which are higher than that of the CMPs with benzene as core. Two ways to release the adsorbed iodine were explored: either slow release into ethanol or quickly release upon heating (with a high degree of control). Spectral studies make us known that the strong affinity for I-2 is mainly due to large porosity, a conjugated pi-electron aromatic system, C-N bonds, and propeller-like twisted structures. Furthermore, luminescent study indicated that TTPA exhibits high sensitivity to electron-deficient I-2 via fluorescence quenching. TTPA shows the largest amount of iodine adsorption and was the first CMP used fluorescence sensing iodine.