期刊
MICROCHIMICA ACTA
卷 185, 期 11, 页码 -出版社
SPRINGER WIEN
DOI: 10.1007/s00604-018-3051-8
关键词
Pseudo-template; Atom transfer radical precipitation polymerization; Surface imprinting; Core-shell; Metal-organic frameworks; Zeolitic imidazolate framework-L; Carbonization; Pretreatment; Magnetic sold phase extraction; Corn sample
资金
- National Natural Science Foundation of China [21575034, 51502079, 21577031, 21775140]
- Fundamental Research Funds for the Henan Provincial Colleges and Universities in Henan University of Technology [2017RCJH10]
A core consisting of nanoporous carbon (MNPC) and magnetized with Co3O4 was coated with a molecularly imprinted polymer (MIP) by atom transfer radical precipitation polymerization. Ethyl 3-coumarincarboxylate was used as a pseudo-template to give a MIP that has a fairly specific recognition capability for aflatoxins. Batch rebinding studies were carried out to determine the specific adsorption equilibrium and specific recognition. Extraction is achieved in a single step by mixing and vortexing the sample extract with the Co-MNPC@ MIP. The loaded nanosorbent was then magnetically separated and eluted with acetonitrile/ water (6/ 4, v/ v). The aflatoxins were then quantified by HPLC. Under optimal conditions, the detection limits for aflatoxins typically are 0.05-0.07 ng mL-1, recoveries from spiked corn are found to be 75.1 to 99.4%, and relative standard deviations range from 1.7 to 5.1 (n = 6).
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