期刊
ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 46, 页码 31669-31676出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b10884
关键词
sodium ion batteries; Prussian blue analogues; cathode materials; nucleation rate; electrolyte; kinetic activation
资金
- National Key Research and Development Program [2016YFB0901501]
- National Natural Science Foundation of China [21373028]
- Joint Funds of the National Natural Science Foundation of China [U1564206]
- Major achievements Transformation Project for Central University in Beijing
- Beijing Science and Technology Project [D151100003015001]
The nucleation rate plays a critical role in the synthesis of Prussian blue analogs. Rapid precipitation may lead to a large number of vacancies and a large amount of interstitial water in the material, resulting in poor electrochemical performance in batteries. Hence, sodium citrate is used to compete with [Fe(CN)(6)](4-) to slow down the coordination rates of Ni2+ and Mn2+ ions with ferrous cyanide ions. The feasibility of the experiment is also confirmed by theoretical analysis. Benefiting from stable crystal structure and the removal of interstitial water, the as-prepared Na2NixMnyFe(CN)(6) sample exhibits a high reversible capacity of 150 mA h g(-1). In addition, a high rate performance of 77 mA h g(-1) is achieved at a current density of 1600 mA g(-1). Most noteworthy, the Coulombic efficiency and specific capacity gradually increase in the first few cycles, which can be ascribed to the formation of a passivation layer on the surface of the electrode. Continuous testing in an electrolyte solution of 1 M NaPF6 dissolved in sulfone reveals that the presence of a passivation film is very important for the stability of the electrode.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据