期刊
ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 36, 页码 23862-23867出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b08257
关键词
pH sensor; organic field-effect transistor; liquid crystal; diblock copolymer; perfusion
资金
- Korean Government (Basic Research Laboratory Program) [2011-0020264]
- Korean Government (Human Resource Training Project for Regional Innovation_MOE) [NRF_2014H1C1A1066748]
- Korean Government (Basic Science Research Program) [2009 - 0093819, NRF_2016H1D5A1910319, NRF_2015R1A2A2A01003743, NRF_2014R1A1A3051165, NRF_2014H1A2A1016454]
We report broadband pH-sensing organic field-effect transistors (OFETs) with the polymer-dispersed liquid crystal (PDLC) sensing layers. The PDLC layers are prepared by spin-coating using ethanol solutions containing 4-cyano-4'-pentyl-biphenyl (503) and a diblock copolymer (PAA-b-PCBOA) that consists of LC-philic block [poly(4-cyanobiphenyl-4-oxyundecyl acrylate) (PCBOA)] and acrylic acid block [poly(acrylic acid) (PAA)]. The spin-coated sensing layers feature of SOB microdoniains (<5 mu m) encapsulated by the PAA-b-PCBOA polymer chains: The resulting LC-integrated-OFETs (PDLC-i-OFETs) can detect precisely and reproducibly a wide range of pH with only small amounts (10-40 mu L) of analyte solutions in both static and dynamic perfusion modes. The positive drain current change is measured for acidic solutions (pH < 7), whereas basic solutions (pH > 7) result in the negative change of drain current. The drain current trend in the present PDLC-i-OFET devices is explained by the shrinking expanding mechanism of the PAA chains in the diblock copolymer layers.
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