期刊
ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 47, 页码 32574-32580出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b09063
关键词
polyethyleneimine; hydrophilic surface; amorphous VOx; perovskite solar cells; interfacial treatment
资金
- National Natural Science Foundation of China [21401167, 91233101, 11174256, 51203166, 51473172, 51473173]
- Fundamental Research Program from the Ministry of Science and Technology of the People's Republic of China [2014CB931704, 2013CB933004, 2011CB932303, 2011CB808400]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDA09020000]
- China Postdoctoral Science Foundation [2013M540573]
- Fundamental and Advanced Technology Research Program from the Science and Technology Department of Henan Province [142300410031.0]
The interfacial contact is critical for the performance of perovskite solar cells (PSCs), leading to dense perovskite thin films and efficient charge transport. In this contribution, an effective interfacial treatment solution using polyethyleneimine (PEI) was developed to improve the performance and stability of PSCs. Inserting PEI between the s-VOx and perovskite layers can produce a high-energy hydrophilic surface to facilitate the formation of a high-quality perovskite layer by the solution method. Accordingly, the surface coverage of perovskite film on the s-VOx layer increased from 80% to 95%, and the PCE of the device improved from 12.06% (with an average of 10.16%) to 14.4% (with an average value of 12.8%) under an irradiance of 100 mW cm(-2) AM 1.5G sunlight. More importantly, the stability of PSCs was further improved after adding another PEI layer between the electron transport layer and LiF/Al layer, less than 10% decay in efficiency during a 10-days observation. Since all layers of the PSCs were fabricated at low temperature (<150 degrees C), these PEI-treated PSCs based on the amorphous VOx layer have the potential to contribute significantly toward the development of efficient and stable solar cells on flexible substrates.
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