期刊
MACROMOLECULES
卷 52, 期 1, 页码 81-87出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.8b02446
关键词
-
资金
- National Science Foundation [CHE-1553780]
- Semiconductor Research Corporation [2016-PK-2666]
- A*STAR Singapore
We report facile and efficient synthesis of macromonomers (MMs) via nitroxide radical coupling (NRC) of a norbornene moiety to the chain end of various polymers prepared using atom transfer radical polymerization (ATRP). The synthesis can be simplified to a one-pot procedure for MMs of polyacrylate homopolymers and block copolymers. The MMs synthesized by this method underwent well-controlled ring-opening metathesis polymerization (ROMP) to almost complete conversions (>90%) to yield brush polymers and block copolymers with low dispersities (<1.2) and high molecular weights (300-3000 kDa). This facile method of MM synthesis provided a range of high-quality MMs, which enabled easy access to diverse well-defined brush multiblock copolymers with different blocks in the backbone and/or side chains.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据