期刊
ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 22, 页码 13673-13677出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b03197
关键词
Chevrel; Mo6S8 nanocubes; Zn battery; Zn2+ intercalation; nondendrite anode; stationary energy storage; polyiodide catholytes
资金
- U.S. Department of Energy (DOE) Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division [KC020105-FWP12152]
- DOE's Office of Biological and Environmental Research
- DOE [DE-AC05-76RL01830]
This work describes the Synthesis of Chevrel phase Mo6S8 nanocubes and its application as the anode material for rechargeable Zn-ion batteries, Mo6S8 can host Zn2+ ions reversibly in both aqueous and nonaqueous electrolytes with specific capacities around 90 mAh/g, and exhibited, remarkable intercalation kinetics and cyclic stability. In addition, we assembled full cells by integrating Mo6S8 anodes, with zinc-polyiodide (I-/I-3(-))-based catholytes, and demonstrated that Such full cells were also able to deliver outstanding rate performance and cyclic stability. This first demonstration of a Zinc-intercalating anode could inspire the design of advanced Zn-ion batteries.
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