4.8 Article

Hydroquinone Resin Induced Carbon Nanotubes on Ni Foam As Binder-Free Cathode for Li-O2 Batteries

期刊

ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 6, 页码 3868-3873

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b10669

关键词

hydroquinone resin; carbon nanotubes; binder free; cathode; Li-O-2 batteries

资金

  1. National Basic Research Program [2014CB932102, 2013CB934102]
  2. National Natural Science Foundation of China [21271128, 21331004, 51472158]
  3. Shanghai Shuguang Program

向作者/读者索取更多资源

In this work, hydroquinone resin was used to grow carbon nanotubes directly on Ni foam. The composites were obtained via a simple carbonization method, which avoids using the explosive gaseous carbon precursors that are usually applied in the chemical vapor deposition method. When evaluated as cathode for Li-O-2 batteries, the binder-free structure showed enhanced ORR/OER activities, thus giving a high rate capability (12690 mAh g(-1) at 200 mA g(-1) and 3999 mAh g(-1) at 2000 mA g(-1)) and outstanding long-term cycling stability (capacity limited 2000 mAh g(-1), 110 cycles at 200 mA g(-1)). The excellent battery performance provides new insights into designing a low-cost and high-efficiency cathode for Li-O-2 batteries.

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