期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 220, 期 1, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201800306
关键词
benzoxazine monomers; double decker silsesquioxanes; layered silicates; polybenzoxazines; polydimethylsiloxanes; polyhedral oligomeric silsesquioxanes; thermal curing polymerizations
资金
- Ministry of Science and Technology, Taiwan [MOST 106-2221-E-110-067-MY3, 105-2221-E-110-092-MY3]
The preparation of organic/inorganic hybrid materials comprising a polybenzoxazine (PBZ) matrix incorporating silicon-based species (e.g., polydimethylsiloxane [PDMS], layered silicates [clays], and polyhedral oligomeric silsesquioxanes [POSS]) and carbon-based materials (e.g., carbon black, carbon fibers, carbon nanotubes, and graphene) has received much attention in recent years because these composites display low water absorption, low surface free energy, low dielectric constants, flame-retardancy, and excellent thermal and mechanical properties. This short review article describes the chemical and physical approaches that are used to prepare PBZs incorporating silica and carbon nanocomposites. In addition, recent reports of their physical properties are discussed, covering their dielectric constants and dynamic mechanical, thermal, electrical, and surface properties.
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