期刊
LANGMUIR
卷 34, 期 50, 页码 15537-15543出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.8b03296
关键词
-
资金
- National Key RD Program [2018YFA0307400]
- UESTC [ZYGX2017KYQD176]
- Opening Project of State Key Laboratory of Polymer Materials Engineering (Sichuan University) [sklpme2018-4-28]
In this report, we designed surfaces with reversible green-light-switched wettability via donor-acceptor Stenhouse adducts (DASAs). Photoresponsive micro/nanoparticles were prepared by coating the surfaces of silica micro/nanoparticles with polydopamine and then postmodifying with DASA molecules. Then, the particles were immobilized on a glass substrate surfaces either with double-sided adhesive tape or cross-linking poly(dimethylsiloxane). Silica micro/nanoparticles with various diameters (0.2, 2.5, and 85 mu m) were used to fabricate the photoresponsive surface. Green light irradiation switches the hydrophobic linear DASA to a hydrophilic cyclic isomer, which further increases the wettability and contact angle hysteresis on the surface. On the other hand, heating (100 degrees C) induces the cyclic-to-linear isomerization of DASA molecules and switches the surface back to hydrophobic. The wettability of the DASA-modified surface is reversible under alternate green light irradiation and heating.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据