期刊
ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 5, 页码 2910-2916出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b10835
关键词
cobalt telluride; hydrogen evolution reaction; branched nanowire; core-shell; electrocatalyst; carbon fiber paper
资金
- National Natural Science Foundation of China [51002115, 51572111]
- Innovation/Entrepreneurship Program of Jiangsu Province [477, 26]
- Fundamental Research Funds for Central University [XJJ2015104]
- Natural Science Foundation of Jiangxi Province [20151BAB206017]
- Aeronautical Science Foundation of China [2013ZF56022]
Cobalt telluride branched nanostructures on carbon fiber paper (CFP) with two different morphologies were synthesized via solution-based conversion reaction. Both the CoTe2 with nanodendrite and CoTe with nanosheet morphologies on the CoTe2 nanotube (CoTe2 NDs/CoTe2 NTs and CoTe NSs/CoTe2 NTs) supported by CFP exhibit high activities toward hydrogen evolution reaction (HER). Particularly, the CoTe NSs/CoTe2 NTs only require an overpotential of 230.0 mV to deliver the current density of 100 mA cm(-2) in acid solution. After cycling for 5000 cycles or 20 h continual electrolysis, only a small performance loss is observed.
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