期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 166, 期 3, 页码 A5210-A5214出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0321903jes
关键词
-
资金
- Research Grants Council of the Hong Kong Special Administrative Region, China [CityU 21202014]
Silicon monoxide is a potential high-capacity anode material for lithium-ion batteries. However, its low initial Coulombic efficiency hinders its adoption in commercial batteries. Here, we use an electrochemical approach, depth of discharge test, to study the origin of the irreversibility in SiO electrodes. We find two contributions to the irreversible capacity of SiO, depending on the reaction products during lithiation. Carbon-coating the material improves the reversible capacity as it increases its electrical conductivity. Disproportionation is an effective way to decrease irreversibility in the initial cycle with the formation of large cluster of SiO2 which is electrochemically inactive. Though, the reversible capacity is reduced. (c) The Author(s) 2018. Published by ECS.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据