期刊
ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 33, 页码 21710-21720出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b07620
关键词
chiral interfaces; integrated polysaccharides; amidation; three-dimensional porous structure; tryptophan isomers
资金
- National Natural Science Foundation of China [21275023]
- Advanced Catalysis and Green Manufacturing Collaborative Innovation Center [ACGM2016-06-27]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
Polysaccharides of sodium carboxymethyl cellulose (CMC) and chitosan (CS) were integrated together via amidation reactions between the carboxyl groups on sodium CMC and the amino groups on CS. Compared with individual sodium CMC and CS, the integrated polysaccharides with a mass ratio of 1:1, CMC-CS (1:1), exhibited a three-dimensional (3D) porous network structure, resulting in a significantly enhanced hydrophility due to the exposed polar functional groups in the CMC-CS (1:1). Chiral interfaces were constructed with the integrated polysaccharides and used for electrochemical enantiorecognition of tryptophan (Trp) isomers. The CMC-CS (1:1) chiral interfaces exhibited excellent selectivity toward the Trp isomers owing to the highly hydrophilic feature of CMC-CS (1:1) and the different steric hindrance during the formation of H bonds between Trp isomers and CMC-CS (1:1). Also, the optimization in the preparation of integrated polysaccharides such as mass ratio and combination mode (amidation or electrostatic interactions) was investigated. The CMC-CS (1:1) presented the ability of determining the percentage of D-Trp in racemic mixtures, and thus, the proposed electrochemical chiral interfaces could be regarded as a potential biosensing platform for enantiorecognition of chiral compounds.
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