4.8 Article

Converting Chemical Energy to Electricity through a Three-Jaw Mini-Generator Driven by the Decomposition of Hydrogen Peroxide

期刊

ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 18, 页码 11403-11411

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b00550

关键词

energy conversion; mini-generator; bubble propulsion; smart device; horizontal locomotion

资金

  1. NSFC [21374006, 51422302]
  2. Program of the Co-Construction with Beijing Municipal Commission of Education of China
  3. Open Project of State Key Laboratory of Supramolecular Structure and Materials [SKLSSM201617]
  4. Beijing Young Talents Plan [YETP0488]

向作者/读者索取更多资源

Energy conversion from a mechanical form to electricity is one of the most important research advancements to come from the horizontal locomotion of small objects. Until now, the Marangoni effect has been the only propulsion method to produce the horizontal locomotion to induce an electromotive force, which is limited to a short duration because of the specific property of surfactants. To solve this issue, in this article we utilized the decomposition of hydrogen peroxide to provide the propulsion for a sustainable energy conversion from a mechanical form to electricity. We fabricated a mini generator consisting of three parts: a superhydrophobic rotator with three jaws, three motors to produce a jet of oxygen bubbles to propel the rotation of the rotator, and three magnets integrated into the upper surface of the rotator to produce the magnet flux. Once the mini generator was placed on the solution surface, the motor catalyzed the decomposition of hydrogen peroxide. This generated a large amount of oxygen bubbles that caused the generator and integrated magnets to rotate at the air/water interface. Thus, the magnets passed under the coil area and induced a change in the magnet flux, thus generating electromotive forces. We also investigated experimental factors, that is, the concentration of hydrogen peroxide and the turns of the solenoid coil, and found that the mini-generator gave the highest output in a hydrogen peroxide solution with a concentration, of 10 wt % and under a coil with 9000 turns. Through combining the stable superhydrophobicity and catalyst, we realized electricity generation for a long duration, which could last for 26 000 s after adding H2O2 only once. We believe this work provides a simple process for the development of horizontal motion and provides a new path for energy reutilization.

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