期刊
ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 20, 页码 12748-12755出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b12784
关键词
ac-line filtering; conducting polymer; electrochemical capacitor; thin film; micro-pseudocapacitor
资金
- King Abdullah University of Science and Technology (KAUST)
- Advanced Nanofabrication, Imaging and Characterization Laboratory at KAUST
In this study, we investigate the frequency response of micro-pseudocapacitors based on conducting polymer electrodes such as poly(3,4-ethylenedioxythiophene) (PEDOT), polypyrrole, and polyaniline. It is shown that by proper choice of polymeric material and device structure, miniaturized micro-pseudocapacitors can match the frequency response of commercial bulky electrolytic capacitors. Specifically, we show that PEDOT-based micro-pseudocapacitors exhibit phase angle of -80.5 degrees at 120 Hz, which is comparable to commercial bulky electrolytic capacitors, but with an order of magnitude higher capacitance density (3 FV/cm(3)). The tradeoff between the areal capacitance (C-A) and frequency response in the two-dimensional architecture (C-A = 0.15 mF/cm(2), phase angle of -80.5 degrees at 120 Hz) is improved by designing three-dimensional thin-film architecture (C-A = 1.3 mF/cm(2), phase angle of -60 degrees at 120 Hz). Our work demonstrates that fast frequency response can be achieved using electroactive polymer electrodes.
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