期刊
ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 37, 页码 24974-24981出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b10542
关键词
microfluidic technology; fluid construction; SERS detection; clustered nanostructures; biomolecule detection
资金
- NSF of China [51172042]
- MOST of China [2012AA030309]
- MOE of China [IRT1221, 111-2-04]
- STC of Shanghai [12 nm0503900, 13JC1400200]
- SRFDP [20110075130001]
- Donghua University [CUSF-DH-D-2013002]
- Eastern Scholar
- Georgia Institute of Technology
- Brook Byers Institute for Sustainable Systems
- China Scholarship Council
A materials fabrication concept based on a fluid construction strategy to create three-dimensional (3D) ZnO@ZnS-Ag active nanostructures at arbitrary position within confined microchannels to form an integrated microfluidic surface enhanced Raman spectroscopy (SERS) system is presented. The fluid-construction process allowed facile construction of the nanostructured substrates, which were shown to possess a substantial number of integrated hot spots that support SERS activity. Finite-difference time-domain (FDTD) analysis suggested that the 3D clustered geometry facilitated hot spot formation. High sensitivity and good recycle performance were demonstrated using 4-mercaptobenzoic acid (4-MBA) and a mixture of Rhodarnine 6G (R6G) and 4-MBA as target organic pollutants to evaluate the SERS microfluidic device performance. The 3D clustered nanostructures were also effective in the detection of a representative nerve agent and biomolecule. The results of this investigation provide a materials and process approach to the fabrication of requisite nanostructures for the online detection of organic pollutants, devices for real-time observation of environmental hazards, and personal-health monitoring.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据