期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 49, 页码 16888-16892出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b09612
关键词
-
资金
- University of Rochester
- NSF [CHE-1708256]
A cobalt-tripeptide complex (CoGGH) is developed as an electrocatalyst for the selective six-electron, eight-proton reduction of nitrite to ammonium in aqueous buffer near neutral pH. The onset potential for nitrite reduction occurs at -0.65 V vs Ag/AgCl (1 M KCl). Controlled potential electrolysis at -0.90 V generates ammonium with a faradaic efficiency of 90 +/- 3% and a turnover number of 3550 +/- 420 over 5.5 h. CoGGH also catalyzes the reduction of the proposed intermediates nitric oxide and hydroxylamine to ammonium. These results reveal that a simple metallopeptide is an active functional mimic of the complex enzymes cytochrome c nitrite reductase and siroheme-containing nitrite reductase.
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