期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 44, 页码 15022-15030出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b09682
关键词
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资金
- Spanish MINECO [PN MAT2015-65354-C2-1-R]
- Catalan AGAUR [2014 SGR 80]
- ERC under the EU-FP7 [ERC-Co 615954]
- CERCA Programme/Generalitat de Catalunya
- Spanish MINECO through the Severo Ochoa Centres of Excellence Programme [SEV-2013-0295]
- Generalitat de Catalunya (EU) [2014 BP-B 00155]
- Generalitat de Catalunya
Herein we report a novel, ozone-based method for postsynthetic generation of mesoporosity in metal-organic frameworks (MOFs). By carefully selecting mixed-ligand Zr-fcu-MOFs based on organic ligand pairs in which one ligand has ozone-cleavable olefin bonds and the other ligand is ozone-resistant, we were able to selectively break the cleavable ligand via ozonolysis to trigger fusion of micropores into mesopores within the MOF framework. This solid-gas phase method is performed at room-temperature, and, depending on the cleavable ligand used, the resultant ligand-fragments can be removed from the ozonated MOF by either washing or sublimation. Compared to the corresponding highly microporous starting MOFs, the highly mesoporous product MOFs exhibit radically distinct gas sorption properties.
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