期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 42, 页码 13566-13569出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b08316
关键词
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资金
- National Science Foundation, Division of Materials Research [1309347]
- RSCA award from CSULB
The [Zn4O](6+) cluster is well-known to form the archetypal MOF-5 topology with dicarboxylate ligands. Here we report two new materials (CPM-300 and -301) that show dramatic alteration of topological and chemical behaviors of [Zn4O](6+) clusters. In CPM-300, [Zn4O](6+) untypically forms the MIL-88/MOF-235 type framework with a small pentane-ring-based chiral dicarboxylate. In contrast, in CPM-301, when mediated by [Zn-9(btz)(12)](6+) clusters (btz = benzotriazolate), the MOF-5 topology is regenerated with the same chiral ligand, albeit with alternating [Zn4O](6+) and [Zn-9(btz)(12)](6+) clusters. Importantly, both CPM-300 and CPM-301 are homochiral, hydrothermally stable in boiling water and alcohol, and thermally stable to 440 degrees C or higher. It is concluded that small methyl groups on the chiral ligand is sufficiently powerful to shield [Zn4O](6+) clusters from degradation by water, even at high temperatures. These results reveal a promising platform for the development of a new class of cluster-based homochiral and hydrothermally stable porous materials.
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