期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 45, 页码 15181-15185出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b09909
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资金
- NIH [R35-GM1217140]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R35GM127140] Funding Source: NIH RePORTER
Enantio- and diastereoselective conjunctive cross-coupling of beta-substituted alkenylboron ate complexes is studied. Whereas beta-substitution shifts the chemoselectivity of the catalytic reaction in favor of the Suzuki-Miyaura product, use of a boronic ester ligand derived from acenaphthoquinone allows the process to favor the conjunctive product, even with substituted substrates.
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