期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 1, 页码 98-103出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b11466
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资金
- Deutsche Forschungsgemeinschaft (DFG), excellent initiative e-conversion (LMU)
- National Natural Science Foundation of China [21602083]
- Fundamental Research Funds for the Central Universities [JUSRP51703A]
- European Research Council under the European Union's Seventh Framework Programme (FP7/2007-2013)/ERC [321339]
The reaction of various organozinc pivalates with anthranils provides anilines derivatives, which cyclize under acidic conditions providing condensed quinolines. Using alkenylzinc pivalates, electron-rich arylzinc pivalates or heterocyclic zinc pivalates produces directly the condensed quinolines of which several structures belong to new heterocyclic scaffolds. These N-heterocycles are of particular interest for organic light emitting diodes with their high photoluminescence quantum yields and long exciton lifetimes as well as for hole-transporting materials in methylammonium lead iodide perovskites solar cells due to an optimal band alignment for holes and a large bandgap.
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