期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 102, 期 6, 页码 3695-3704出版社
WILEY
DOI: 10.1111/jace.16158
关键词
cobalt; colour; nickel; phosphates; solid solutions
资金
- Ministerio de Ciencia, Innovacion y Universidades [MAT2013-40950-R, MAT2016-78155-C2-1-R]
- ERDF
NH4[Co1-yNiyPO4]H2O (0y1) single crystals were fired to prepare Co2-xNixP2O7 0x2 solid solutions between 800 and 1200 degrees C. The structure of these solid solutions is -M2P2O7 (M = Co, Ni). The contraction of the unit cell with increasing x confirmed the formation of these solid solutions. The UV-vis-NIR spectra of these solid solutions were consistent with Co(II) and Ni(II) ions in the two different crystallographic sites (octahedral site and square pyramidal site) in the -M2P2O7 structure. Due to their thermal stability, Co2-xNixP2O7 (0x2) solid solutions with -M2P2O7 structure can be used as a blue, green, brown or yellow ceramic pigment.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据