期刊
ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 23, 页码 14604-14612出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b03803
关键词
single walled carbon nanohorns; dye sensitized solar cells; cobalt redox mediators; electrochemical impedance spectroscopy; PEDOT
资金
- Italian Ministero dell'Universita e della Ricerca (MIUR) [FIRE RBAP11C58Y]
- PRIN Hi-Phuture
- PRIN DSSCX
The electrochemical properties of both pristine single walled carbon nanohorns (SWCNHS) and their chemically oxidized form (ox-SWCNHS) spray coated onto fluorine doped SnO2 (FTO) were investigated in the framework of the fabrication of cobalt based transparent dye sensitized solar cells (DSSCs). These new nanocarbon substrates, evaluated in conjunction with the Co(bpy)(3)(2+/3+) (bpy = 2,2'-bipyridine) redox mediator, are endowed with excellent electrocatalytic properties, ease of fabrication, and very promising stability and display a great potential for replacing the best noble metal and conductive polymer catalytic materials in the building of semitransparent counter electrodes in new generation photoelectrochemical devices.
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