期刊
ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 34, 页码 22196-22200出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b06158
关键词
branched nanocrystals; alloys; galvanic replacement reaction; enzyme-free biosensors; glucose detection
资金
- Washington State University, USA
By carefully controlling the synthesis condition, branched PtCu bimetallic templates were synthesized in aqueous solution. After the galvanic replacement reaction between PtCu templates and the Pt precursors, PdCuPt trimetallic nanocrystals with branched structures were obtained. Owing to the open structure and the optimized composition, the electrochemical experimental results reveal that the PdCuPt trimetallic nanocrystals possess high electrocatalytic activity, selectivity and stability for the oxidation of glucose in alkaline solution. In detail, a detection limit of 1.29 mu M and a sensitivity of 378 mu A/mM/cm(2) are achieved. The good electrocatalytic performance should be attributed to the unique branched nanostructure as well as the synergistic effect among metals. The superior catalytic properties suggest that these nanocrystals are promising for enzyme-free detection of glucose.
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