期刊
JOURNAL OF POWER SOURCES
卷 409, 期 -, 页码 24-30出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2018.10.092
关键词
Potassium ion battery; Graphite; Ether-based electrolyte; Carbonate-based electrolyte; Solid electrolyte interphase
资金
- National Natural Science Foundation of China [51502032, 51502007, 51672007]
- National Key Research and Development Program of China [2018YFA0306100]
- Fundamental Research Funds for the Central Universities, China [ZYGX2016J044]
- Opening Project of State Key Laboratory of Advanced Chemical Power Sources [SKL-ACPS-C-12]
The graphite as the potassium ion battery anode is studied in KPF6-EC/DMC and KPF6-DME electrolytes. It is found that the graphite demonstrates superior rate performance with a capacity of 87 mAh g(-1) at a current rate of 10 C (corresponding to 2.8 A g(-1)) and excellent capacity retention ability of 84% after 3500 cycles in DME-based electrolyte. Moreover, its initial coulombic efficiency is 87.4%, higher than 69.6% in EC/DMC-based electrolyte. The K+ solvating with DME complexes co-intercalate into graphite leading a high operational voltage at similar to 0.7 V vs. similar to 0.2 V in carbonate-based electrolyte, a fast apparent K+ diffusion coefficient of 10(-8) cm(2) s(-1), a negligible solid-electrolyte interface film, a small volume expansion (7.7% in (002) plane vs. 63% in EC/DMC electrolyte). This study addresses the importance of electrolyte in altering the potassium storage mechanisms to tune the energy density and power density in potassium ion batteries (KIBs).
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