期刊
JOURNAL OF POWER SOURCES
卷 410, 期 -, 页码 10-14出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2018.10.070
关键词
ZnO@Bi/C sphere; Synergistic effect; High specific capacity; Zn-Ni battery
资金
- National Natural Science Foundation of China [51674301]
ZnO@Bi/C sphere with a distinctive core-shell construct is designed and fabricated by using solvothermal method, which is applied as a novel electrode material of Zn-Ni battery for the first time. The analytical results manifest that the core of the ZnO@Bi/C sphere coated with carbon layer consists of a large number of ZnO nanoparticles (NPs), and in situ modified metal Bi is embedded in the amorphous carbon layer and ZnO NP core uniformly, thereby forming a unique core-shell construct. Unlike pure ZnO anode, the ZnO@Bi/C sphere shows more remarkable specific capacity and cycling stability: that is, after cycling 180 times at 1 C, the discharge specific capacity remains at 630.7 mAh g(-1). The excellent electrochemical properties are attributed to the synergistic effect of carbon and metal Bi in the ZnO@Bi/C sphere, which is conducive to decreasing the voltage polarization and promoting the battery reversibility.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据