期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 57, 期 1, 页码 7-12出版社
WILEY
DOI: 10.1002/pola.29266
关键词
dynamic covalent polymerization; inverse vulcanization; nucleophilic activation; organocatalysis; sulfur
资金
- NSF [DMR-1607971, CHE-1305773]
- NRF for the National Creative Research Initiative Center for Intelligent Hybrids [2010-0018290]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1305773] Funding Source: National Science Foundation
The accelerator effect of amine activators N-methylimidazole and 4-vinylaniline (4-VA) on inverse vulcanization and dynamic covalent polymerization (DCP) has been investigated. The sulfur polymer with self-activation comonomer 4-VA could also be used for low temperature DCP to incorporate some volatile monomers. Those approaches provide a new synthetic and rate accelerated processes to activate S-8 for copolymerization processes with functional comonomers at lower temperatures and under a broader range of reaction conditions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据