期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 123, 期 3, 页码 1904-1912出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.8b11673
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资金
- Deutsche Forschungsgemeinschaft [HA 1893/16]
- Russian Academy of Science [AAAA-A17-117041710084-2]
Within the family of metal organic frameworks, the zeolite-imidazolate framework (ZIF) of type ZIF-8 is among the most promising materials with potential application for hydrocarbon separation, notably of alkanes and alkenes. We have applied NMR spectroscopy for exploring the interaction of representative alkane/alkene mixtures with the host framework as well as the mobility of the various components in their mixture. Deviating from, for example, the separation patterns known for MFI-based membranes, the mobility of the faster molecules (alkenes) is found to remain essentially unaffected by the presence of more slowly diffusing molecules (alkanes). In addition, H-2 and Zn-67 magic-angle spinning NMR contributes to the characterization of ZIF-8 in search for guest-induced changes in the lattice structure.
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