期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 3, 页码 1588-1595出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b02661
关键词
-
资金
- National Natural Science Foundation of China [21602167, 21871218]
- Natural Science Basic Research Plan in Shaanxi Province of China [2016JQ2019, 2015JQ2050]
- China Postdoctoral Science Foundation [2015M580830, 2014M550484, 2015T81013]
- Fundamental Research Funds for the Central Universities
- Key Laboratory Construction Program of Xi'an Municipal Bureau of Science and Technology [201805056ZD7CG40]
Alkynylcyclopropanes have been used for the first time as coupling partners in transition-metal-catalyzed C-H functionalization. Specifically, a Cp*Rh-III-catalyzed regioselective annulation of alkynylcyclopropanes with N-aryloxyamides via redox-neutral C-H/C-C activation has been developed, which affords highly functionalized 2,3-dihydrobenzofurans bearing an (E)-exocyclic carbon-carbon double bond and a tetra-substituted carbon center in moderate to good yields with a broad substrate scope.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据