期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 22, 页码 13707-13715出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01965
关键词
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资金
- SERB, New-Delhi [EMR/2016/006358]
- CSIR, New-Delhi [02(0226)15/EMR-II]
- UGC
- Indian Institute of Science
- R. L. Fine Chem
We present an approach to utilize water as the hydride source via Pd(II)/Pd(0) catalysis. As a case study, we have achieved a diboron mediated Pd(II)-catalyzed hydroarylation of alkynes using arylboronic acids. This approach not only complements conventional reactivity of Pd via Pd(0)/Pd(II) cycle for the hydroarylation but also utilizes water as the hydride source. We believe this would particularly be beneficial in utilizing water as a reagent.
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