期刊
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
卷 29, 期 23, 页码 19932-19941出版社
SPRINGER
DOI: 10.1007/s10854-018-0123-9
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资金
- National Natural Science Foundation of China [51364024, 51404124]
- Foundation for Innovation Groups of Basic Research in Gansu Province [1606RJIA322]
A novel composite with embedded cobalt nanoparticles in nitrogen doped carbon (Co@NDC) is synthesized by the in-situ reduction of Co(OH)(2) using ionic liquid [HMIm]N(CN)(2) as carbon precursor. Due to the special structure, this composite can form more stable solid electrolyte interface (SEI) film than cobalt nanoparticles when used as anode. The Co@NDC electrode shows a high discharge capacity of 1322mAhg(-1) after 850 cycles at 0.5C, and an extremely long cycle life (436mAhg(-1) after 2400 cycles at 5C). This excellent electrochemical performance can be attributed to the catalytic lithium-carbon reaction of cobalt nanoparticles, high conductivity of the carbon material, and the thin and stable SEI film.
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