期刊
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
卷 35, 期 6, 页码 994-1002出版社
JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2018.12.021
关键词
Li-rich cathode oxide material; Oxygen vacancy; Solvothermal method; Electrochemical performance
资金
- National Key Research and Development Program [2017YFA0402800]
- National Natural Science Foundation of China [U1732160, 11504380]
A couple of layered Li-rich cathode materials Li1.2Mn0.54Ni0.13Co0.13O2 without any carbon modification are successfully synthesized by solvothermal and hydrothermal methods followed by a calcinationprocess. The sample synthesized by the solvothermal method (S-NCM) possesses more homogenous microstructure, lower cation mixing degree and more oxygen vacancies on the surface, compared to thesample prepared by the hydrothermal method (H-NCM). The S-NCM sample exhibits much better cycling performance, higher discharge capacity and more excellent rate performance than H-NCM. At 0.2 C rate, the S-NCM sample delivers a much higher initial discharge capacity of 292.3 mAh g(-1) and the capacity maintains 235 mAh g(-1) after 150 cycles (80.4% retention), whereas the corresponding capacity values are only 269.2 and 108.5 mAh g(-1) (40.3% retention) for the H-NCM sample. The S-NCM sample also shows the higher rate performance with discharge capacity of 118.3 mAh g(-1) even at a high rate of 10 C, superior to that (46.5 mAh g(-1)) of the H-NCM sample. The superior electrochemical performance of the S-NCM sample can be ascribed to its well-ordered structure, much larger specific surface area and much more oxygen vacancies located on the surface. (c) 2019 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
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