期刊
JOURNAL OF MASS SPECTROMETRY
卷 53, 期 12, 页码 1214-1221出版社
WILEY
DOI: 10.1002/jms.4299
关键词
carbon dioxide; carbon monoxide; catalysis; electrochemical CO2 reduction reaction; interfering gases; mass spectrometry; multivariate calibration; nitrogen
资金
- Swiss Innovation Agency lnnosuisse: Swiss Competence Center for Energy Research (SCCER) BIOSWEET and Heat and Electricity Storage
A multivariate calibration method for mass spectrometry is presented that enables a quantitative analysis of gas mixtures containing interfering gases that contribute to the same mass-to-charge ratios at nominal resolution. Multiple calibration gas mixtures with linearly independent compositions are used in order to obtain the calibration constants for the contribution of each gas to each of the mass-to-charge ratio peaks. The method was successfully applied to the quantitative detection of CO in a mixture with CO2 and N-2, which represents a difficulty commonly encountered in heterogeneous catalysis and electrocatalysis research.
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