Constructing efficient mixed-ion perovskite solar cells based on TiO2 nanorod array

Oriented TiO2 nanorod array (TiO2 NA) is very attractive in the fields of halide perovskite solar cells (PSCs) due to its fewer grain boundaries and high crystallinity for effective charge collection. The optimization of TiO2 nanostructures has been proved to be an effective approach for efficient PSCs. On the other hand, tuning the crystallization of perovskite films on top of the TiO2 NA is very important for efficient TiO2-NA based PSCs. Herein, scanning electron microscopy (SEM) and X-ray powder diffraction (XRD) were used to study the crystallization of different mixed-ion Cs-0.1(FA(0.83)MA(0.17))(0.9)Pb(I0.83Br0.17)(3) perovskite (in which MA = CH3NH3+ and FA = CH(NH2)(2)(+)) films, from different perovskite precursor concentrations, on the TiO2 nanorod arrays. A mechanism was proposed to reveal the inherent connection between the precursor concentration and the crystallite growth of the perovskite film prepared with anti solvent quenching process. Meanwhile, both faster charge separation at perovskite/TiO2 NA interface and longer charge transport were observed on thicker perovskite film with larger grains, revealed by the time-resolved method. However, atomic force microscopy (AFM) results indicated that too thick perovskite film impaired the charge collection owing to the increased recombination. By balancing the charge collection and film thickness, highly efficient PSC5 were prepared with a champion power conversion efficiency (PCE) of 19.33% with little hysteresis. The study highlights a great potential of incorporating oriented one-dimensional electron extraction materials in high-performance PSCs and other applications. (C) 2018 Elsevier Inc. All rights reserved.