期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 533, 期 -, 页码 598-603出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2018.08.094
关键词
Ag nanoparticles; Peptoid; Peptide; Aggregation; Self-assembly
资金
- Russell Berrie Nanotechnology Institute (RBNI)
We report a unique example of Ag(0) nanoparticles (NPs)-assemblies stabilized by 2,2-bipyridine (BP), via the incorporation of BP at the N-terminus of a peptoid heptamer bearing phenylethyl groups in the other positions. We show that this peptoid mediates the aggregation of the Ag(0) NPs into nanochain-like assemblies. Transmission electron microscopy, supported by UV-Vis spectroscopy analysis, revealed pre-assembly of the BP-peptoid oligomers into elongated pearl-like morphology, which serve as a template for the NPs. The fact that completely synthetic biomimetic oligomers can template and control the assembly of metal NPs, and specifically Ag(0), represents a conceptual mimic of the interaction between biomolecules and minerals for the production of nanostructured inorganic materials with complex morphologies. (C) 2018 Elsevier Inc. All rights reserved.
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