期刊
JOURNAL OF CHROMATOGRAPHY A
卷 1583, 期 -, 页码 39-47出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.chroma.2018.11.016
关键词
o-Hydroxyazobenzene; m-Trihydroxybenzene; Porous organic polymer; Adsorbent; Phenylurea herbicides
资金
- National Natural Science Foundation of China [31571925, 31471643, 31671930]
- Natural Science Foundation of Hebei Province [B2016204136, B2016204146, B2017204025]
- Advanced Programs for the Introduction of Overseas Scholars by Hebei Province [CL201713]
- Hebei Double First Class Discipline Construction Foundation for the Discipline of Food Science and Engineering of Hebei Agricultural University [2016SPGCA18]
This work presents a simple and eco friendly synthetic approach to fabricate a novel o-hydroxyazobenzene porous organic polymer (HAzo-POP) by diazo-coupling of 2,6-diaminoanthraquinone with m-trihydroxybenzene in aqueous solution. The prepared HAzo-POP possesses good stability and high adsorption capability towards aromatic organic pollutants due to its porous nature, highly conjugated structure and strong hydrogen bonding ability. The HAzo-POP was successfully used for the solid-phase extraction of phenylurea herbicides from six real samples prior to high performance liquid chromatography with ultraviolet detection. The analytical method showed good linearity in the range of 0.5-160.0 ng g(-1) for celery, lettuce and tomato samples, and 0.4-160.0 ng mL(-1) for milk, soybean milk and juice samples, with low limits of detection in the range from 0.05 to 0.30 ng g(-1) (or mL(-1)). The HAzo POP has a promising application potential for the adsorption of more aromatic organic compounds. (C) 2018 Elsevier B.V. All rights reserved.
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