4.7 Article

Enhanced thermoelectric performance of BiSbTe alloy: Energy filtering effect of nanoprecipitates and the effect of SiC nanoparticles

期刊

JOURNAL OF ALLOYS AND COMPOUNDS
卷 784, 期 -, 页码 1276-1283

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.01.084

关键词

Thermoelectric properties; BiSbTe alloy; Nanoprecipitates; Energy filtering; SiC nanoparticles

资金

  1. National Natural Science of China [U1504511, 51371076, 51571083, 11674083]
  2. Science and Technology fund of Henan Province [182102210227, 162102210169, 162300410224]
  3. Foundation of Henan Educational Committee [14A430029]

向作者/读者索取更多资源

p-type Bi0.46Sb1.54Te3 samples containing nanoprecipitates are prepared by mechanical alloying (MA) and spark plasma sintering (SPS) technique. The thermoelectric performance of Bi0.46Sb1.54Te3 is improved by the energy filtering effect induced by nanoprecipitates, leading to a high ZT value of 1.18 at 325 K. To further improve the thermoelectric performance of Bi0.46Sb1.54Te3, SiC nanoparticles are dispersed into Bi0.46Sb1.54Te3 matrix. The addition of SiC simultaneously increases the electrical conductivity and the Seebeck coefficient. Meanwhile, it also decreases the lattice thermal conductivity from 0.38 to 0.33 Wm(-1) K-1 for the 0.2 wt% SiC sample. Consequently, a maximum ZT value of 1.45 at 325 K is obtained for Bi0.46Sb1.54Te3 with the addition of 0.2 wt% SiC composites, which increases about 23% than the pristine sample. (C) 2019 Elsevier B.V. All rights reserved.

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