期刊
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
卷 19, 期 11, 页码 -出版社
MDPI
DOI: 10.3390/ijms19113532
关键词
electron paramagnetic resonance; EPR; multifrequency EPR; high-spin cobalt complex; resolution of A-mid
资金
- NIH NIBIB [P41 EB001980]
Low-frequency electron paramagnetic resonance (EPR) is used to extract the EPR parameter A-mid and support the approximate X-band value of g-mid for Ba(CoyZn1/3-yTa2/3)O-3. Although the cobalt hyperfine structure for the |+/- 1/2 > state is often unresolved at X-band or S-band, it is resolved in measurements on this compound. This allows for detailed analysis of the molecular orbital for the |+/- 1/2 > state, which is often the ground state. Moreover, this work shows that the EPR parameters for Co substituted into Zn compounds give important insight into the properties of zinc binding sites.
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