期刊
EUROPEAN POLYMER JOURNAL
卷 109, 期 -, 页码 360-366出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2018.10.005
关键词
Cyclization; MALDI-TOF MS; Polycondensation; Ring-opening polymerization; Polylactide
资金
- Elantas AG, Hamburg
Starting from dibutyltin oxide, four catalysts were synthesized, namely the dibutyltin bisphenoxides of phenol (SnPh), 4-chlorophenol (SnCP), 4-hydroxybenzonitrile (SnCN) and pentafluorophenol (SnOPF). With the first three catalysts polymerizations of L-lactide at 160 degrees C in bulk yielded large fraction of linear chains having phenylester end groups at short reaction times. At longer times the fraction of cycles considerably increased at the expense of the linear chains, when SnCN was used as catalyst. With SnOPF only cyclic polylactides were obtained at low Lac/Cat ratios ( < 400) with weight average molecular weights (Mw) up to 90 000 Da, whereas for high Lac/Cat ratios mixtures of cyclic and linear chains were found. Polymerizations in solution enabled variation of the molecular weight. Polymerizations of meso-lactide at temperatures down to 60 degrees C mainly yielded even-numbered linear chains supporting the postulated ROPPOC mechanism.
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